Formation of quinoxaline and benzimidazole derivatives from methylpentoses by the reaction with O-phenylenediamine.
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چکیده
منابع مشابه
Histogranin-like antinociceptive and anti-inflammatory derivatives of o-phenylenediamine and benzimidazole.
Histogranin (HN)-like nonpeptides were designed and synthesized using benzimidazole (compound 1) and o-phenylenediamine (compounds 2-7) as scaffolds for the attachment of phenolic hydroxyl and basic guanidino pharmacophoric elements present in HN. The benzimidazole derivative N-5-guanidinopentanamide-(2R)-yl-2-(p-hydroxybenzyl)-5-carboxybenzimidazole (1) and the o-phenylenediamine derivative N-...
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15 صفحه اول5-sulfosalicylic acid as an efficient organocatalyst for environmentally benign synthesis of 2-substituted benzimidazoles
A water soluble, Bronsted acid, 5-sulfosalicylic acid as an efficient organocatalyst was used for the synthesis of physiologically active 2-substituted benzimidazole derivatives from o-phenylenediamine and aromatic aldehydes in ethanol at reflux condition. Cost-effectiveness, use of non-hazardous solvents, metal free and commercially available catalyst, single-step, environmentally fri...
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Dicarbonyl sugars were separated by capillary electrophoresis as o-phenylenediamine derivatives (quinoxalines). Tetrabutylammonium bromide was used as a modifier; n-arabino-2-hexosulose (n-glucosone), D-lyxo-2-hexostdose (D-gdaCtOSOnC), 7-deoxy-L-galacto-2-hexosulose and 5-hydroxy-2,3dioxohexanal served as standards. The separation procedure was optimized with respect to pH, buffer and solute c...
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ژورنال
عنوان ژورنال: Agricultural and Biological Chemistry
سال: 1984
ISSN: 0002-1369,1881-1280
DOI: 10.1271/bbb1961.48.2753